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- W2904878681 abstract "Rare earth (RE)-based phosphors with mesoporous structure that can improve the absorption and utilization of light have attracted much attention recently. Herein, we develop a novel and facile self-template strategy to synthesize honeycomb-like mesoporous YPO4:Ln3+ (Ln = Eu, Tb) phosphors using Y4O(OH)9NO3: Ln3+ as the precursor through a simple H3PO4 etching process. The maximum specific surface area of the mesoporous YPO4:Ln3+ phosphors can reach 406 m2 g−1. The influence of mesoporous structure, crystallinity, and the concentration of rare earth ions on the photoluminescence performance of mesoporous YPO4:Ln3+ phosphors was investigated. The results of fluorescence measurements indicate the mesoporous YPO4:Ln3+ phosphors exhibit better photoluminescence performance after calcination at 900 °C due to the large surface area and high crystallinity. The optimum doped concentrations of Eu3+ ions and Tb3+ ions are 0.12 and 0.08, respectively, and the concentration quenching occurs among nearest-neighbor ions. This work provide a new sight on preparation of phosphors for white light-emitting diodes lamps." @default.
- W2904878681 created "2018-12-22" @default.
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- W2904878681 date "2019-04-01" @default.
- W2904878681 modified "2023-10-16" @default.
- W2904878681 title "Self-template construction of honeycomb-like mesoporous YPO4:Ln3+ (Ln = Eu, Tb) phosphors with tuneable luminescent properties" @default.
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- W2904878681 doi "https://doi.org/10.1016/j.jallcom.2018.12.107" @default.
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