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• W2904908593 abstract "Abstract Explorations on a mixed metal phosphatoantimonate system led to the discovery of two new anhydrous phosphatoantimonates, namely, Cs 4 MSb 6 P 4 O 28 (M=Mg, Zn), which represent the first examples of quinary A I – M II –Sb V – P V – O systems. Single-crystal structure analysis reveals that the two title compounds crystallize in the tetragonal space group I 4 1 / a (No. 88). Their structures feature complicated 3D frameworks with interesting tunnel structures comprised of corner sharing MO 4 tetrahedra, SbO 6 octahedra and PO 4 tetrahedra, with the Cs + cations sitting in the tunnels to balance the valence. Optical reflectance spectrum measurements show that these two compounds are insulators with band gaps of about 4.5 eV." @default.
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• W2904908593 date "2018-12-14" @default.
• W2904908593 modified "2023-10-16" @default.
• W2904908593 title "Unique 3D framework formed by adding MIIO4 groups into high Sb/P ratio phosphatoantimonates" @default.
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• W2904908593 doi "https://doi.org/10.1515/zkri-2018-2137" @default.
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