Matches in SemOpenAlex for { <https://semopenalex.org/work/W2904927199> ?p ?o ?g. }
- W2904927199 endingPage "95" @default.
- W2904927199 startingPage "85" @default.
- W2904927199 abstract "Metal–organic frameworks with highly ordered porosity have been studied extensively. In this paper, the effect of framework (pore) disorder on the gas sorption of azole-based isoreticular Cu(II) MOFs with rtl topology and characteristic 1D tubular pore channels is investigated for the first time. In contrast to other isoreticular rtl metal–organic frameworks, the Cu(II) metal–organic framework based on 5-(1 H -imidazol-1-yl)isophthalate acid has a crystallographically identifiable disordered framework without open N-donor sites. The framework provides a unique example for investigating the effect of pore disorder on gas sorption that can be systematically evaluated. It exhibits remarkable temperature-dependent hysteretic CO 2 sorption up to room temperature, and shows selectivity of CO 2 over H 2 , CH 4 and N 2 at ambient temperature. The unique property of the framework is its disordered structure featuring distorted 1D tubular channels and DMF-guest-remediated defects. The results imply that structural disorder (defects) may play an important role in the modification of the performance of the material." @default.
- W2904927199 created "2018-12-22" @default.
- W2904927199 creator A5002170896 @default.
- W2904927199 creator A5006907432 @default.
- W2904927199 creator A5009733897 @default.
- W2904927199 creator A5013466769 @default.
- W2904927199 creator A5019868466 @default.
- W2904927199 creator A5024841956 @default.
- W2904927199 creator A5027268662 @default.
- W2904927199 creator A5076159048 @default.
- W2904927199 date "2019-01-01" @default.
- W2904927199 modified "2023-10-18" @default.
- W2904927199 title "Framework disorder and its effect on selective hysteretic sorption of a T-shaped azole-based metal–organic framework" @default.
- W2904927199 cites W1159525283 @default.
- W2904927199 cites W1943588217 @default.
- W2904927199 cites W1963799153 @default.
- W2904927199 cites W1963982737 @default.
- W2904927199 cites W1965944206 @default.
- W2904927199 cites W1968732311 @default.
- W2904927199 cites W1969360633 @default.
- W2904927199 cites W1976408176 @default.
- W2904927199 cites W1977941554 @default.
- W2904927199 cites W1978139832 @default.
- W2904927199 cites W1978683707 @default.
- W2904927199 cites W1984705290 @default.
- W2904927199 cites W1987632972 @default.
- W2904927199 cites W1991586238 @default.
- W2904927199 cites W1991852895 @default.
- W2904927199 cites W1996369650 @default.
- W2904927199 cites W1997581138 @default.
- W2904927199 cites W1999351214 @default.
- W2904927199 cites W2003545182 @default.
- W2904927199 cites W2003759419 @default.
- W2904927199 cites W2004235923 @default.
- W2904927199 cites W2007157592 @default.
- W2904927199 cites W2008487021 @default.
- W2904927199 cites W2010697328 @default.
- W2904927199 cites W2011338778 @default.
- W2904927199 cites W2013207280 @default.
- W2904927199 cites W2016967039 @default.
- W2904927199 cites W2020322901 @default.
- W2904927199 cites W2020772475 @default.
- W2904927199 cites W2021767761 @default.
- W2904927199 cites W2022085591 @default.
- W2904927199 cites W2023694170 @default.
- W2904927199 cites W2036056432 @default.
- W2904927199 cites W2038440906 @default.
- W2904927199 cites W2038902537 @default.
- W2904927199 cites W2039964133 @default.
- W2904927199 cites W2047480702 @default.
- W2904927199 cites W2048720451 @default.
- W2904927199 cites W2049281675 @default.
- W2904927199 cites W2052865601 @default.
- W2904927199 cites W2054817589 @default.
- W2904927199 cites W2055087733 @default.
- W2904927199 cites W2059665237 @default.
- W2904927199 cites W2062904068 @default.
- W2904927199 cites W2065288194 @default.
- W2904927199 cites W2073188805 @default.
- W2904927199 cites W2080939210 @default.
- W2904927199 cites W2082637983 @default.
- W2904927199 cites W2091161882 @default.
- W2904927199 cites W2092379373 @default.
- W2904927199 cites W2093946771 @default.
- W2904927199 cites W2094145140 @default.
- W2904927199 cites W2099331042 @default.
- W2904927199 cites W2099486431 @default.
- W2904927199 cites W2100716186 @default.
- W2904927199 cites W2101187042 @default.
- W2904927199 cites W2102410614 @default.
- W2904927199 cites W2103215073 @default.
- W2904927199 cites W2105218596 @default.
- W2904927199 cites W2105631122 @default.
- W2904927199 cites W2106278247 @default.
- W2904927199 cites W2113510568 @default.
- W2904927199 cites W2125121626 @default.
- W2904927199 cites W2126026588 @default.
- W2904927199 cites W2126599373 @default.
- W2904927199 cites W2128141951 @default.
- W2904927199 cites W2130360607 @default.
- W2904927199 cites W2133654354 @default.
- W2904927199 cites W2136139798 @default.
- W2904927199 cites W2138179856 @default.
- W2904927199 cites W2144616899 @default.
- W2904927199 cites W2145687597 @default.
- W2904927199 cites W2147717613 @default.
- W2904927199 cites W2155507399 @default.
- W2904927199 cites W2155596290 @default.
- W2904927199 cites W2156324674 @default.
- W2904927199 cites W2159078042 @default.
- W2904927199 cites W2162148042 @default.
- W2904927199 cites W2167742169 @default.
- W2904927199 cites W2207880418 @default.
- W2904927199 cites W2295616126 @default.
- W2904927199 cites W2313618219 @default.
- W2904927199 cites W2313915764 @default.
- W2904927199 cites W2317061210 @default.
- W2904927199 cites W2318032369 @default.