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• W2904959892 startingPage "2505" @default.
• W2904959892 abstract "The high catalytic reactivity of homoleptic tris(alkyl) lanthanum La{C(SiHMe2)3}3 is highlighted by C−O bond cleavage in the hydroboration of esters and epoxides at room temperature. The catalytic hydroboration tolerates functionality typically susceptible to insertion, reduction, or cleavage reactions. Turnover numbers (TON) up to 10 000 are observed for aliphatic esters. Lanthanum hydrides, generated by reactions with pinacolborane, are competent for reduction of ketones but are inert toward esters. Instead, catalytic reduction of esters requires activation of the lanthanum hydride by pinacolborane." @default.
• W2904959892 created "2018-12-22" @default.
• W2904959892 creator A5015422195 @default.
• W2904959892 creator A5018293360 @default.
• W2904959892 date "2019-01-25" @default.
• W2904959892 modified "2023-09-27" @default.
• W2904959892 title "Interconverting Lanthanum Hydride and Borohydride Catalysts for C=O Reduction and C−O Bond Cleavage" @default.
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• W2904959892 doi "https://doi.org/10.1002/anie.201813305" @default.
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