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• W2904983984 endingPage "779" @default.
• W2904983984 startingPage "769" @default.
• W2904983984 abstract "Herein we have developed a Ni-catalyzed protocol for the synthesis of linear ketones. Aryl, alkyl, and heteroaryl ketones as well as alcohols yielded the monoselective ketones in up to 90% yield. The catalytic protocol was successfully applied in to a gram-scale synthesis. For a practical utility, applications of a steroid derivative, oleyl alcohol, and naproxen alcohol were employed. Preliminary catalytic investigations involving the isolation of a Ni intermediate and defined Ni-H species as well as a series of deuterium-labeling experiments were performed." @default.
• W2904983984 created "2018-12-22" @default.
• W2904983984 creator A5021823749 @default.
• W2904983984 creator A5058836983 @default.
• W2904983984 creator A5073888763 @default.
• W2904983984 date "2018-12-14" @default.
• W2904983984 modified "2023-10-01" @default.
• W2904983984 title "Nickel-Catalyzed Alkylation of Ketone Enolates: Synthesis of Monoselective Linear Ketones" @default.
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• W2904983984 doi "https://doi.org/10.1021/acs.joc.8b02609" @default.
• W2904983984 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30548070" @default.
• W2904983984 hasPublicationYear "2018" @default.
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