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• W2905054443 startingPage "7965" @default.
• W2905054443 abstract "A diphosphination of 1,3-dienes with tetraaryldiphosphines proceeds under Ir(ppy)3-promoted photoredox catalysis to form the corresponding 1,4-diphosphino-2-butenes in good yields with good regioselectivity. The key to success is the addition of a Br+ additive. Subsequent double bond hydrogenation successfully delivers the 1,4-bis(diphenylphosphino)butane (DPPB) derivatives with uniquely large bite angles. Thus, the present method can provide a facile access to DPPB-type ligands, which are of great importance in transition metal catalysis, from readily available diene substrates." @default.
• W2905054443 created "2018-12-22" @default.
• W2905054443 creator A5023893245 @default.
• W2905054443 creator A5028632795 @default.
• W2905054443 creator A5084443222 @default.
• W2905054443 date "2018-12-06" @default.
• W2905054443 modified "2023-10-17" @default.
• W2905054443 title "Diphosphination of 1,3-Dienes with Diphosphines under Visible-Light-Promoted Photoredox Catalysis" @default.
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• W2905054443 doi "https://doi.org/10.1021/acs.orglett.8b03534" @default.
• W2905054443 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30520640" @default.
• W2905054443 hasPublicationYear "2018" @default.
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