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- W2905062891 abstract "The electro-catalyzed oxygen reduction and evolution reactions (ORR/OER) are the key elements of many energy conversion systems, such as fuel cells, water electrolyzers, and rechargeable metal–air batteries. Structural design of durable non-noble nanomaterials as bifunctional OER/ORR catalysts is a major drawback to commercial applications. Herein, we exposed a strongly coupled hybrid material comprising of NiFeP-cubes nanoparticles supported on three-dimensional interconnected Fe,N-decorated carbon (3D-FeNC) as a robust bifunctional ORR/OER catalyst. The strongly coupled NiFeP@3D-FeNC catalyst shows better electron and mass transfer capability, exposure of abundant ORR/OER active sites on the surface, and strongly coupled effects. Accordingly, the as-prepared NiFeP@3D-FeNC catalyst exhibits robust ORR activity (half-wave potential of 0.84 V vs reversible hydrogen electrode) and OER performance (over-potential 0.25 V@10 mA cm–2) in alkaline media. Significantly, the oxygen electrode prepared from the NiFeP@3D-FeNC catalyst further demonstrated superior charge/discharge behavior and long-lasting rechargeability than the benchmark Pt/C + IrO2 catalyst in rechargeable zinc–O2 batteries. This approach opens up a new avenue for the synthesis and advanced the hybrid nanomaterials for various applications." @default.
- W2905062891 created "2018-12-22" @default.
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- W2905062891 date "2018-12-13" @default.
- W2905062891 modified "2023-10-16" @default.
- W2905062891 title "Three-Dimensional Fe,N-Decorated Carbon-Supported NiFeP Nanoparticles as an Efficient Bifunctional Catalyst for Rechargeable Zinc–O<sub>2</sub> Batteries" @default.
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- W2905062891 doi "https://doi.org/10.1021/acsami.8b16126" @default.
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