FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2905113722> ?p ?o ?g. }

• W2905113722 endingPage "739" @default.
• W2905113722 startingPage "730" @default.
• W2905113722 abstract "Oxygen vacancy is conducive to molecular oxygen adsorption and activation, and it is necessary to estimate its contribution on catalysts, especially the doped system for volatile organic compound (VOC) oxidation. Herein, a series of doped Mn xZr1- xO2 catalysts with oxygen vacancy were prepared by partially substituting Zr4+ in a zirconia with low-valent manganese (Mn2+). Compared with the corresponding mechanically mixed samples (MB-x) without oxygen vacancy, Mn xZr1- xO2 catalysts exhibited better toluene conversion and specific reaction rate, where the differential values were calculated to estimate the contribution of oxygen vacancy on catalytic performance. The increase in oxygen vacancy concentrations in Mn xZr1- xO2 catalysts can boost the differential values, implying the enhancement of oxygen vacancy contribution. Density functional theory (DFT) calculations further confirmed the contribution of oxygen vacancy, and molecular oxygen is strongly absorbed and activated on a defective Mn-doped c-ZrO2 (111) surface with oxygen vacancy rather than a perfect m-ZrO2 (-111) surface or a perfect Mn-doped c-ZrO2 (111) surface, thus resulting in the significant improvement in catalytic activity for toluene oxidation. In situ DRIFTS spectra revealed that the oxygen vacancy can alter the toluene degradation pathway and accelerate the intermediates to convert into CO2 and H2O, thus leading to a low activation energy and high specific reaction rate." @default.
• W2905113722 created "2018-12-22" @default.
• W2905113722 creator A5004954920 @default.
• W2905113722 creator A5013162647 @default.
• W2905113722 creator A5025142988 @default.
• W2905113722 creator A5043352173 @default.
• W2905113722 creator A5060780866 @default.
• W2905113722 creator A5072426545 @default.
• W2905113722 date "2018-12-07" @default.
• W2905113722 modified "2023-10-11" @default.
• W2905113722 title "Defective Mn<i>_x</i>Zr_1–<i>x</i>O₂ Solid Solution for the Catalytic Oxidation of Toluene: Insights into the Oxygen Vacancy Contribution" @default.
• W2905113722 cites W1443569211 @default.
• W2905113722 cites W1867742573 @default.
• W2905113722 cites W1983820397 @default.
• W2905113722 cites W1983822274 @default.
• W2905113722 cites W1988692181 @default.
• W2905113722 cites W1997221202 @default.
• W2905113722 cites W2001200641 @default.
• W2905113722 cites W2013658618 @default.
• W2905113722 cites W2027523237 @default.
• W2905113722 cites W2030136791 @default.
• W2905113722 cites W2041170068 @default.
• W2905113722 cites W2055641102 @default.
• W2905113722 cites W2061014335 @default.
• W2905113722 cites W2061070241 @default.
• W2905113722 cites W2081730020 @default.
• W2905113722 cites W2089240244 @default.
• W2905113722 cites W2089381280 @default.
• W2905113722 cites W2117870137 @default.
• W2905113722 cites W2120743069 @default.
• W2905113722 cites W2127723049 @default.
• W2905113722 cites W2145584100 @default.
• W2905113722 cites W2162733257 @default.
• W2905113722 cites W2278037356 @default.
• W2905113722 cites W2320497903 @default.
• W2905113722 cites W2321336759 @default.
• W2905113722 cites W2326512478 @default.
• W2905113722 cites W2338966395 @default.
• W2905113722 cites W2396932017 @default.
• W2905113722 cites W2547690708 @default.
• W2905113722 cites W2573899674 @default.
• W2905113722 cites W2593005772 @default.
• W2905113722 cites W2602814551 @default.
• W2905113722 cites W2604241944 @default.
• W2905113722 cites W2611723064 @default.
• W2905113722 cites W2611902947 @default.
• W2905113722 cites W2619579705 @default.
• W2905113722 cites W2623457846 @default.
• W2905113722 cites W2626643727 @default.
• W2905113722 cites W2675994789 @default.
• W2905113722 cites W2746293124 @default.
• W2905113722 cites W2750736564 @default.
• W2905113722 cites W2761885704 @default.
• W2905113722 cites W2769560688 @default.
• W2905113722 cites W2769673927 @default.
• W2905113722 cites W2771270222 @default.
• W2905113722 cites W2773351401 @default.
• W2905113722 cites W2794662762 @default.
• W2905113722 cites W2797801176 @default.
• W2905113722 cites W2802462977 @default.
• W2905113722 cites W2803174065 @default.
• W2905113722 cites W2884526765 @default.
• W2905113722 cites W2889882450 @default.
• W2905113722 cites W4230419100 @default.
• W2905113722 doi "https://doi.org/10.1021/acsami.8b17062" @default.
• W2905113722 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30523684" @default.
• W2905113722 hasPublicationYear "2018" @default.
• W2905113722 type Work @default.
• W2905113722 sameAs 2905113722 @default.
• W2905113722 citedByCount "213" @default.
• W2905113722 countsByYear W29051137222019 @default.
• W2905113722 countsByYear W29051137222020 @default.
• W2905113722 countsByYear W29051137222021 @default.
• W2905113722 countsByYear W29051137222022 @default.
• W2905113722 countsByYear W29051137222023 @default.
• W2905113722 crossrefType "journal-article" @default.
• W2905113722 hasAuthorship W2905113722A5004954920 @default.
• W2905113722 hasAuthorship W2905113722A5013162647 @default.
• W2905113722 hasAuthorship W2905113722A5025142988 @default.
• W2905113722 hasAuthorship W2905113722A5043352173 @default.
• W2905113722 hasAuthorship W2905113722A5060780866 @default.
• W2905113722 hasAuthorship W2905113722A5072426545 @default.
• W2905113722 hasConcept C114221277 @default.
• W2905113722 hasConcept C147597530 @default.
• W2905113722 hasConcept C147789679 @default.
• W2905113722 hasConcept C152365726 @default.
• W2905113722 hasConcept C161790260 @default.
• W2905113722 hasConcept C178790620 @default.
• W2905113722 hasConcept C179104552 @default.
• W2905113722 hasConcept C185592680 @default.
• W2905113722 hasConcept C192562407 @default.
• W2905113722 hasConcept C2778142098 @default.
• W2905113722 hasConcept C49040817 @default.
• W2905113722 hasConcept C540031477 @default.
• W2905113722 hasConcept C57863236 @default.
• W2905113722 hasConcept C8010536 @default.
• W2905113722 hasConcept C95121573 @default.
• W2905113722 hasConceptScore W2905113722C114221277 @default.

• next