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• W2905175324 abstract "Facile preparation of the α- C-vinyl and -aryl glycosides has been developed via mild Ni-catalyzed reductive vinylation and arylation of C1-glycosyl halides with vinyl/aryl halides. Good to high α-selectivities were achieved for C-glucosides, galactosides, maltoside, and mannosides, which were dictated by the employment of pyridine type ligands. As such, the present work represents unprecedented control for a high level of α-selectivity for C-vinyl-glucosides using cross-coupling approaches and offers hitherto optimal α-selective preparation of C-aryl glucosides via catalyst-controlled coupling strategies." @default.
• W2905175324 created "2018-12-22" @default.
• W2905175324 creator A5007859420 @default.
• W2905175324 creator A5087473417 @default.
• W2905175324 date "2018-12-10" @default.
• W2905175324 modified "2023-10-17" @default.
• W2905175324 title "Stereoselective Preparation of α-<i>C</i>-Vinyl/Aryl Glycosides via Nickel-Catalyzed Reductive Coupling of Glycosyl Halides with Vinyl and Aryl Halides" @default.
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• W2905175324 doi "https://doi.org/10.1021/acs.orglett.8b03567" @default.
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