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- W2905194893 abstract "A new oxide NaCu3Fe2Os2O12 is synthesized using high pressure and temperature conditions. The Rietveld structural analysis shows that the compound possesses both A- and B-site ordered quadruple perovskite structure in Pn3̅ symmetry. The valence states of transition metals are confirmed to be Cu2+/Fe3+/Os5.5+. The three transition metals all take part in magnetic interactions and generate strong Cu2+(↑)Fe3+(↑)Os5.5+(↓) ferrimagnetic superexchange interactions with a high Curie temperature about 380 K. Electrical transport measurements suggest its half-metallic properties. The first-principles theoretical calculations demonstrate that the compound has a spin-down conducting band and a spin-up insulating band with a wide energy gap." @default.
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- W2905194893 date "2018-12-11" @default.
- W2905194893 modified "2023-10-18" @default.
- W2905194893 title "High-Temperature Ferrimagnetic Half Metallicity with Wide Spin-up Energy Gap in NaCu<sub>3</sub>Fe<sub>2</sub>Os<sub>2</sub>O<sub>12</sub>" @default.
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- W2905194893 doi "https://doi.org/10.1021/acs.inorgchem.8b02404" @default.
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