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- W2905605824 abstract "A completely regioselective and highly stereoselective palladium-catalyzed intramolecular hydroarylation of arenesulfonyl ynamines to benzothiazoles was developed. The presence of an electron-withdrawing group on the triple bond of the sulfonyl ynamine was crucial for the success of the reaction and our mechanistic studies suggest an alkyne-directed 5-exo-dig cyclization pathway. The products easily underwent photoinduced rearrangement to 3-amino-1-benzothiophene-1,1-diones (up to 35 % yields after two steps)." @default.
- W2905605824 created "2019-01-01" @default.
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- W2905605824 date "2018-10-10" @default.
- W2905605824 modified "2023-10-04" @default.
- W2905605824 title "Synthesis of 3-Amino-1-benzothiophene-1,1-diones by Alkyne Directed Hydroarylation and 1/N→3/C-Sulfonyl Migration" @default.
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- W2905605824 doi "https://doi.org/10.1002/ejoc.201801062" @default.
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