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- W2905653251 abstract "This research presents the first example of catalytic enantioselective Michael addition reactions between 1-(1-(phenylsulfonyl)vinylsulfonyl)benzene and detrifluoroacetylatively in situ generated 3-fluorooxindole-derived enolates. The optimal catalyst includes Cu(OTf)2 and (1S,2S)-1,2-diphenylethane-1,2-diamine featuring NHR functionalities. The reactions are conducted in THF at -20 °C using DIPEA as a base. The additions show reasonably high degree of structural generality and, therefore, synthetic value for preparation of a new family of compounds possessing pharmacophoric 3-fluorooxindole moiety, solofeaturing quaternary C-F stereogenic center." @default.
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- W2905653251 date "2019-03-01" @default.
- W2905653251 modified "2023-09-30" @default.
- W2905653251 title "Catalytic enantioselective Michael addition reactions between in situ detrifluoroacetylatively generated 3-fluorooxindole-derived enolates and 1-(1-(phenylsulfonyl)vinylsulfonyl)benzene" @default.
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- W2905653251 doi "https://doi.org/10.1016/j.jfluchem.2018.12.009" @default.
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