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- W2905683310 abstract "The asymmetric total synthesis of (−)-epiquinamide has been achieved starting from a 5-iodofuranoside synthon derived from d-glucose. The methods featured Bernet-Vasella reaction followed by Horner-Wadsworth-Emmons (HWE) reaction to provide a new chiral building block diene as the key steps. The bicyclic framework of this quinolizidine was constructed by selective reduction of α,β-unsaturated ester, intramolecular nucleophilic substitution and ring-closing metathesis." @default.
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- W2905683310 date "2019-01-01" @default.
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- W2905683310 title "A new approach to asymmetric synthesis of (−)-epiquinamide from d-glucose" @default.
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- W2905683310 doi "https://doi.org/10.1016/j.tet.2018.12.045" @default.
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