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- W2905805983 abstract "Abstract A catalyst-free reaction of 1-(N-acylamino)alkyltriphenylphosphonium tetrafluoroborates with silyl enolates was developed to prepare β-amino carbonyl compounds. The reported method is a useful approach for the preparation of N-protected β-amino esters as well as N-protected β-amino ketones. The starting 1-(N-acylamino)alkyltriphenylphosphonium tetrafluoroborates are readily available from N-protected α-amino acids. Therefore, the presented approach can be considered a new method for the α-homologation of N-protected α-amino acids to prepare β-amino acid derivatives." @default.
- W2905805983 created "2019-01-01" @default.
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- W2905805983 date "2019-02-01" @default.
- W2905805983 modified "2023-10-18" @default.
- W2905805983 title "Catalyst-free Mannich-type reaction of 1-(N-acylamino)alkyltriphenylphosphonium salts with silyl enolates" @default.
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- W2905805983 doi "https://doi.org/10.1016/j.tet.2018.12.042" @default.
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