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• W2905822328 endingPage "13623" @default.
• W2905822328 startingPage "13619" @default.
• W2905822328 abstract "Abstract A facile, stereoselective method for the synthesis of both carbon‐ and P‐chirogenic phosphine oxides and phosphines bearing a hydroxyl chelating arm was developed. A carefully designed oxaphospholane was constructed via tandem Arbuzov‐ intramolecular cyclization reaction, using commercially available compounds. Regioselective ring opening alkylation/arylation provided optically active phosphine oxides within two synthetic steps. An additional step of stereospecific deoxygenation produced P‐chirogenic tertiary phosphines in high dr." @default.
• W2905822328 created "2019-01-01" @default.
• W2905822328 creator A5077678949 @default.
• W2905822328 creator A5081702374 @default.
• W2905822328 date "2018-12-21" @default.
• W2905822328 modified "2023-09-30" @default.
• W2905822328 title "A Concise Stereoselective Route to <i>C-</i> and <i>P</i> - Chirogenic Hydroxypropyl Phosphines by Ring-Opening of Optically Active Oxaphospholane-2-oxide" @default.
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• W2905822328 doi "https://doi.org/10.1002/slct.201803804" @default.
• W2905822328 hasPublicationYear "2018" @default.
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