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- W2905830187 abstract "The [FeFe]-hydrogenase model, [(μ-bdt)Fe2(CO)6] (1, bdt = benzene-1,2-dithiolato), displays distinctive activity from its analogous complex, [(μ-edt)Fe2(CO)6] (2, edt = ethane-1,2-dithiolato), for electrochemical CO2 reduction in acetonitrile with methanol or water as proton source. The maximum turnover frequency of 195 s–1 estimated for 1 is more than 4800 times higher than that of 2. The influence of reaction conditions on faradaic yield and product selectivity was investigated. Controlled potential electrolysis experiments of 1 under optimal conditions gave a good faradaic yield of 88%, with formic acid as major product (selectivity ≈81%) together with a small amount of CO (selectivity ≈ 11%) and H2 (selectivity ≈ 8%). Density functional theory calculations suggest a mechanism of bimetal synergistic catalysis for electrochemical CO2 reduction by 1." @default.
- W2905830187 created "2019-01-01" @default.
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- W2905830187 creator A5091760648 @default.
- W2905830187 date "2018-12-20" @default.
- W2905830187 modified "2023-09-28" @default.
- W2905830187 title "Chemical Versatility of [FeFe]-Hydrogenase Models: Distinctive Activity of [μ-C<sub>6</sub>H<sub>4</sub>-1,2-(κ<sup>2</sup>-S)<sub>2</sub>][Fe<sub>2</sub>(CO)<sub>6</sub>] for Electrocatalytic CO<sub>2</sub> Reduction" @default.
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- W2905830187 doi "https://doi.org/10.1021/acscatal.8b03921" @default.
- W2905830187 hasPublicationYear "2018" @default.
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