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• W2906073193 abstract "The aim of the present work is to synthesize a zeolite-based catalyst with a hollow morphology and highly dispersed metal nanoparticles (NPs) encapsulated inside the zeolite micropores. For this purpose, we have studied a treatment using tetraalkylammonium (TAA) bromides for the selective removal of a large Pt particle from the outer surface of a hollow Beta zeolite. TEM analysis reveals that we succeeded in the synthesis of a hollow beta zeolite single crystal with encapsulated particles, with a high dispersion of 50-60 %. The molecular-sieve-type mechanism of the obtained catalysts was evaluated in the model reaction of toluene and mesitylene catalytic hydrogenation. Thanks to the high dispersion. a 10-fold activity enhancement has been obtained with respect to hollow beta zeolites with encapsulated NPs recently described in the literature." @default.
• W2906073193 created "2019-01-01" @default.
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• W2906073193 date "2019-01-30" @default.
• W2906073193 modified "2023-10-15" @default.
• W2906073193 title "Hydrogenation Size-Selective Pt/Hollow Beta Catalysts" @default.
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• W2906073193 doi "https://doi.org/10.1002/chem.201805041" @default.
• W2906073193 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30575150" @default.
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