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- W2906095102 abstract "Owing to their abilities to assemble and organize a large number of redox and photoactive components in highly ordered periodic fashion, crystalline porous metal-organic frameworks (MOFs) have the potential to execute myriad complex functions, including charge transport and light to electrical energy conversion when the required conditions are fulfilled. Herein, we demonstrate an unprecedented spontaneous solvothermal growth of precisely [100]-oriented pillared porphyrin framework-11 (PPF-11) films featuring vertically aligned Zn-tetrakis(4-carboxyphenyl)porphyrin (ZnTCPP) walls and horizontally aligned 2,2'-dimethyl-4,4'-bipyridine beams attached to annealed ZnO-fluorine-doped tin oxide (FTO) surfaces and their remarkable photovoltaic performance in liquid-junction solar cells. The [100]-oriented PPF-11/ZnO-FTO photoanodes displayed excellent photovoltaic response (short-circuit current ( JSC): 4.65 mA/cm2, open-circuit voltage ( VOC): 470 mV, power conversion efficiency: 0.86%) that easily outperformed all control devices as well as previously reported porphyrin and Ru(bpy)32+-based visible light-harvesting MOFs with 10-1000 times greater photocurrent density and 2-375 times higher efficiency. The superior photovoltaic behavior of [100]-oriented PPF-11/ZnO films compared to epitaxially grown MOF thin films on insulating self-assembled monolayers and drop-cast PPF films with different orientations can be attributed to several factors, including better charge separation, transport, and injection capabilities of the former. The noncatenated PPF-11 was able to host electron-deficient C60 guests, filling in nearly half of its cavities and engage them in ZnTCPP/C60 charge-transfer interaction. However, the C60-doped PPF-11/ZnO films displayed much weaker photovoltaic response than undoped [100]-oriented PPF-11/ZnO films presumably due to exclusion of I-/I3- electrolyte from the C60-occupied cavities and the inability of isolated C60 guests to support long-range charge movement." @default.
- W2906095102 created "2019-01-01" @default.
- W2906095102 creator A5026577184 @default.
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- W2906095102 date "2018-12-25" @default.
- W2906095102 modified "2023-09-29" @default.
- W2906095102 title "Efficient MOF-Sensitized Solar Cells Featuring Solvothermally Grown [100]-Oriented Pillared Porphyrin Framework-11 Films on ZnO/FTO Surfaces" @default.
- W2906095102 cites W1693102551 @default.
- W2906095102 cites W1780208875 @default.
- W2906095102 cites W1823292607 @default.
- W2906095102 cites W1964676341 @default.
- W2906095102 cites W1980138378 @default.
- W2906095102 cites W1985184540 @default.
- W2906095102 cites W1995004090 @default.
- W2906095102 cites W1998905594 @default.
- W2906095102 cites W1999184653 @default.
- W2906095102 cites W1999937609 @default.
- W2906095102 cites W2002102470 @default.
- W2906095102 cites W2003430253 @default.
- W2906095102 cites W2005010430 @default.
- W2906095102 cites W2031090109 @default.
- W2906095102 cites W2047612475 @default.
- W2906095102 cites W2051860949 @default.
- W2906095102 cites W2056896873 @default.
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- W2906095102 cites W2070278096 @default.
- W2906095102 cites W2073059073 @default.
- W2906095102 cites W2078122806 @default.
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- W2906095102 cites W2080615437 @default.
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- W2906095102 cites W2093710037 @default.
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- W2906095102 cites W2111493705 @default.
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- W2906095102 cites W2120517672 @default.
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- W2906095102 cites W2329728470 @default.
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- W2906095102 cites W2335046847 @default.
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- W2906095102 cites W2520631701 @default.
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- W2906095102 doi "https://doi.org/10.1021/acsami.8b17807" @default.
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