FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2906202203> ?p ?o ?g. }

• W2906202203 endingPage "1635" @default.
• W2906202203 startingPage "1627" @default.
• W2906202203 abstract "Here we report the steady state kinetic analysis of field-effect-controlled outer-sphere electrochemistry on ultrathin back-gated ZnO working electrodes (i.e., 5 nm ZnO electrodes prepared on SiO2/degenerate Si back gates). To achieve steady state conditions in the electrolyte phase, gate-tunable electrochemical flow cells were prepared by integrating a silicone microfluidic channel on the back-gated ZnO electrode. In these flow cells, continuous supply of fresh electrolyte generates time-invariant diffusion layers near the ZnO surface, allowing steady-state kinetic analysis as in other hydrodynamic methods. From the steady-state analysis, it was found that the electron density on the ZnO surface increases with the voltage bias, VBG, applied to the back gate, while the rate constant for electron transfer decreases with VBG. The observed trend can be explained as a result of the field-effect-induced band alignment shift at the ZnO/electrolyte interface which is predicted by our conceptual model; a positive back gate bias shifts the conduction band edge down at a given working electrode potential, leading to an increased surface electron density on ZnO, but simultaneously less overlap of the band edge with the electron acceptor states in solution, which means a lower electron transfer rate constant. Overall, the results quantitatively demonstrate that back gates and the ensuing field effect can be used to control kinetics of interfacial electron transfer at two-dimensional (2D) semiconductor electrodes." @default.
• W2906202203 created "2019-01-01" @default.
• W2906202203 creator A5058426570 @default.
• W2906202203 creator A5071975512 @default.
• W2906202203 creator A5087231379 @default.
• W2906202203 date "2018-12-20" @default.
• W2906202203 modified "2023-10-15" @default.
• W2906202203 title "Continuous and Reversible Tuning of Electrochemical Reaction Kinetics on Back-Gated 2D Semiconductor Electrodes: Steady-State Analysis Using a Hydrodynamic Method" @default.
• W2906202203 cites W1594749659 @default.
• W2906202203 cites W1939544938 @default.
• W2906202203 cites W1957696535 @default.
• W2906202203 cites W1965395195 @default.
• W2906202203 cites W1968496011 @default.
• W2906202203 cites W1974078786 @default.
• W2906202203 cites W1974896731 @default.
• W2906202203 cites W1977279162 @default.
• W2906202203 cites W1977744295 @default.
• W2906202203 cites W1988443925 @default.
• W2906202203 cites W1989000814 @default.
• W2906202203 cites W1989923975 @default.
• W2906202203 cites W1993533051 @default.
• W2906202203 cites W2000072726 @default.
• W2906202203 cites W2005356006 @default.
• W2906202203 cites W2010442211 @default.
• W2906202203 cites W2010965076 @default.
• W2906202203 cites W2040253216 @default.
• W2906202203 cites W2059362080 @default.
• W2906202203 cites W2062146054 @default.
• W2906202203 cites W2068686056 @default.
• W2906202203 cites W2078166949 @default.
• W2906202203 cites W2080870150 @default.
• W2906202203 cites W2083088477 @default.
• W2906202203 cites W2095114847 @default.
• W2906202203 cites W2103274508 @default.
• W2906202203 cites W2119989570 @default.
• W2906202203 cites W2133795748 @default.
• W2906202203 cites W2140668337 @default.
• W2906202203 cites W2158932701 @default.
• W2906202203 cites W2160321223 @default.
• W2906202203 cites W2409819892 @default.
• W2906202203 cites W2768170262 @default.
• W2906202203 cites W2785684308 @default.
• W2906202203 doi "https://doi.org/10.1021/acs.analchem.8b05216" @default.
• W2906202203 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30569706" @default.
• W2906202203 hasPublicationYear "2018" @default.
• W2906202203 type Work @default.
• W2906202203 sameAs 2906202203 @default.
• W2906202203 citedByCount "13" @default.
• W2906202203 countsByYear W29062022032019 @default.
• W2906202203 countsByYear W29062022032020 @default.
• W2906202203 countsByYear W29062022032021 @default.
• W2906202203 countsByYear W29062022032022 @default.
• W2906202203 countsByYear W29062022032023 @default.
• W2906202203 crossrefType "journal-article" @default.
• W2906202203 hasAuthorship W2906202203A5058426570 @default.
• W2906202203 hasAuthorship W2906202203A5071975512 @default.
• W2906202203 hasAuthorship W2906202203A5087231379 @default.
• W2906202203 hasConcept C108225325 @default.
• W2906202203 hasConcept C113196181 @default.
• W2906202203 hasConcept C123669783 @default.
• W2906202203 hasConcept C147789679 @default.
• W2906202203 hasConcept C17525397 @default.
• W2906202203 hasConcept C185592680 @default.
• W2906202203 hasConcept C192562407 @default.
• W2906202203 hasConcept C43617362 @default.
• W2906202203 hasConcept C49040817 @default.
• W2906202203 hasConcept C52859227 @default.
• W2906202203 hasConcept C68801617 @default.
• W2906202203 hasConcept C8171440 @default.
• W2906202203 hasConceptScore W2906202203C108225325 @default.
• W2906202203 hasConceptScore W2906202203C113196181 @default.
• W2906202203 hasConceptScore W2906202203C123669783 @default.
• W2906202203 hasConceptScore W2906202203C147789679 @default.
• W2906202203 hasConceptScore W2906202203C17525397 @default.
• W2906202203 hasConceptScore W2906202203C185592680 @default.
• W2906202203 hasConceptScore W2906202203C192562407 @default.
• W2906202203 hasConceptScore W2906202203C43617362 @default.
• W2906202203 hasConceptScore W2906202203C49040817 @default.
• W2906202203 hasConceptScore W2906202203C52859227 @default.
• W2906202203 hasConceptScore W2906202203C68801617 @default.
• W2906202203 hasConceptScore W2906202203C8171440 @default.
• W2906202203 hasFunder F4320337392 @default.
• W2906202203 hasIssue "2" @default.
• W2906202203 hasLocation W29062022031 @default.
• W2906202203 hasLocation W29062022032 @default.
• W2906202203 hasOpenAccess W2906202203 @default.
• W2906202203 hasPrimaryLocation W29062022031 @default.
• W2906202203 hasRelatedWork W1987674700 @default.
• W2906202203 hasRelatedWork W2027279228 @default.
• W2906202203 hasRelatedWork W2044740642 @default.
• W2906202203 hasRelatedWork W2087248011 @default.
• W2906202203 hasRelatedWork W2159779271 @default.
• W2906202203 hasRelatedWork W2335008604 @default.
• W2906202203 hasRelatedWork W2406618687 @default.
• W2906202203 hasRelatedWork W2953250471 @default.
• W2906202203 hasRelatedWork W3137452781 @default.
• W2906202203 hasRelatedWork W780397172 @default.
• W2906202203 hasVolume "91" @default.

• next