Matches in SemOpenAlex for { <https://semopenalex.org/work/W2906393414> ?p ?o ?g. }
- W2906393414 endingPage "833" @default.
- W2906393414 startingPage "821" @default.
- W2906393414 abstract "A one-pot synthetic procedure for a series of bimetallic Nb/M complexes, Cl–Nb(iPrNPPh2)3M–X (M = Fe (2), Ni (4), Cu (5)), is described. A similar procedure aimed at synthesizing a Nb/Co analogue instead affords iPrN═Nb(iPrNPPh2)2(μ-PPh2)Co–I (3) through cleavage of one phosphinoamide P–N bond under reducing conditions. Complexes 4 and 5 are found to have short Nb-M distances, corresponding to unusual metal–metal bonds between Nb and these first row transition metals. For comparison, a series of heterobimetallic O≡Nb(iPrNPPh2)3M–X complexes (M = Fe (7), Co (8), Ni (9), Cu (10)) was synthesized. In these complexes, the NbV center is engaged in sufficient π-bonding to the terminal oxo ligand to remove the driving force for direct metal–metal interactions. A comparison of the cyclic voltammograms of 2 and 4–10 reveals that the presence of a second metal shifts the redox potentials of both Nb and the late metal center anodically, even when direct metal–metal interactions are not present." @default.
- W2906393414 created "2019-01-01" @default.
- W2906393414 creator A5007485073 @default.
- W2906393414 creator A5019257746 @default.
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- W2906393414 creator A5034523608 @default.
- W2906393414 creator A5052171520 @default.
- W2906393414 creator A5057394997 @default.
- W2906393414 creator A5088343251 @default.
- W2906393414 creator A5089209632 @default.
- W2906393414 date "2018-12-20" @default.
- W2906393414 modified "2023-10-15" @default.
- W2906393414 title "Assessing the Metal–Metal Interactions in a Series of Heterobimetallic Nb/M Complexes (M = Fe, Co, Ni, Cu) and Their Effect on Multielectron Redox Properties" @default.
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- W2906393414 doi "https://doi.org/10.1021/acs.inorgchem.8b02960" @default.