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- W2906406961 abstract "We report a system with ethylene-bridged flavinium salt 2b which catalyzes the aerobic oxidation of toluenes and benzyl alcohols with high oxidation potential (Eox > +2.5 V vs SCE) to give the corresponding benzoic acids under visible light irradiation. This is caused by the high oxidizing power of excited 2b (E(2b*) = +2.67 V vs SCE) involved in photooxidation and by the accompanying dark organocatalytic oxygenation provided by the in situ formed flavin hydroperoxide 2b-OOH." @default.
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- W2906406961 date "2018-12-24" @default.
- W2906406961 modified "2023-10-15" @default.
- W2906406961 title "Combining Flavin Photocatalysis and Organocatalysis: Metal-Free Aerobic Oxidation of Unactivated Benzylic Substrates" @default.
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- W2906406961 doi "https://doi.org/10.1021/acs.orglett.8b03547" @default.
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