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- W2907439476 abstract "Molecule-based ferroelectrics are a class of highly desirable intelligent materials for their highly variable physical properties, easy and environmentally friendly processing, especial light weight and mechanical flexibility. 4-Aminopyridinium Perchlorate (APP), used to be known as a pyroelectric below 243 K, is first discovered to be a new molecular ferroelectric in this work, which has a perfect electric hysteresis loops with a large spontaneous polarization of 1.0 μC/cm2 and a small coercive field of 0.67 kV/cm below 246 K. Owing to the dramatic changes of the protonated cations and order–disorder of anions, the crystal symmetry of APP transforms from P21/c to P21 in this first-order phase transition, which is revealed by other measurements, such as differential scanning calorimetry, heat capacity, dielectric anomalies and Raman spectrum." @default.
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- W2907439476 date "2019-02-01" @default.
- W2907439476 modified "2023-09-25" @default.
- W2907439476 title "The ferroelectric properties of 4-aminopyridinium perchlorate" @default.
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- W2907439476 doi "https://doi.org/10.1016/j.cplett.2018.12.044" @default.
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