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- W2907520816 abstract "The switching behavior of fast ion conducting AgI-Ag2O-MoO3 glasses has been investigated thoroughly, over a wide range of compositions within the glass forming region, proportioning a balance between glass matrix former (MoO3) and glass matrix expander (AgI), in order to understand the switching mechanism of bulk samples with inert electrode. The ion transport, the agility to reach the threshold voltage (Vth), Vth-composition (x) profile and thickness dependence of Vth have been explained in the light of Mott-Gurney model for electric field driven thermally activated ion hopping. A feature of alteration in memory behavior from reversible to irreversible, due to a change in electrode type from active to passive has been observed and discussed. Being a decoupled system, the Vth-x profile exhibits a seemingly scattered nature while the glass transition temperature (Tg)-x profile increases monotonically, indicating a growing network connectivity. These two profiles together narrow down the composition region where the most thermally stable, fast switching performing samples, with a minimum power loss lie. During switching, a metallic filament forms between the two electrodes. Raman and Energy-dispersive X-ray spectroscopy studies find no traces of molybdenum, oxygen and electrode material in the filament. Scanning electron microscopic images show a bubble formation in the vicinity of anode-electrolyte interface which is analogous to oxidation reaction; however, no evidence of an anionic transport has been found. This in turns helps us to understand the corrosion mechanism in the glass matrix due to the electrochemical process. Overall, the present work aims to understand some crucial issues regarding the memory behavior of AgI-Ag2O-MoO3 glasses to enable us to exploit the material for non-volatile memory applications." @default.
- W2907520816 created "2019-01-11" @default.
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- W2907520816 date "2018-12-22" @default.
- W2907520816 modified "2023-09-27" @default.
- W2907520816 title "Memory Switching Behavior of bulk Fast Ion Conducting AgI-Ag2O-MoO3 Glasses" @default.
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