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- W2907556411 abstract "Incorporating specific functionalities within the framework offers a significant opportunity to effectively improve gas capture ability and selectivity of MOFs. In this work, by employing oxo-centered trinuclear metal cluster and an amide-functionalized tetracarboxylate ligand (5-(3,5-dicarboxybenzamido)-isophthalic acid) (H4L), we have delicately constructed an indium based soc-MOF, [In3(μ3-O)(L)1.5(H2O)3][NO3]·5H2O·EtOH·1.5DMF (1). Benefited from its integrated structural features (i.e. open metal sites, narrow and amide-functionalized channels), 1 demonstrates high CO2 uptake (119.0 cm3 g−1 at 1 bar and 273 K) as well as excellent selectivity for CO2 over N2 (23.0 at 273 K). Moreover, enhanced high water stability makes 1 promising material for the water adsorption." @default.
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- W2907556411 date "2019-03-01" @default.
- W2907556411 modified "2023-10-18" @default.
- W2907556411 title "Enhanced water stability and selective carbon dioxide adsorption of a soc-MOF with amide-functionalized linkers" @default.
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- W2907556411 doi "https://doi.org/10.1016/j.poly.2018.12.048" @default.
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