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- W2907694590 abstract "Abstract We investigate magnetic properties of mixed crystals of spinel oxides Zn(Cr1−xFex)2O4 and Cd(Cr1−xFex)2O4 to study Cr-site substitution effects on the geometrically-frustrated magnetism of chromite spinels ZnCr2O4 and CdCr2O4. Zn(Cr1−xFex)2O4 and Cd(Cr1−xFex)2O4 with above x ∼ 0.1 exhibit spin-glass-like behavior below ∼10 K which is suppressed by magnetic field H > 1 kOe. Moreover, the Fe concentration x dependence of Weiss temperature ΘW in Zn(Cr1−xFex)2O4 (Cd(Cr1−xFex)2O4) exhibits the sign change of ΘW from negative below x ∼ 0.4 (x ∼ 0.1) to positive above x ∼ 0.4 (x ∼ 0.1). This suggests that, in Zn(Cr1−xFex)2O4 and Cd(Cr1−xFex)2O4, the competition of antiferromagnetic and ferromagnetic interactions (bond frustration) becomes stronger with increasing the Fe concentration x, while the geometrical frustration becomes weaker with increasing x." @default.
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- W2907694590 date "2019-04-01" @default.
- W2907694590 modified "2023-09-27" @default.
- W2907694590 title "Substitution effects on frustrated magnetism of chromite spinel ACr2O4 (A = Zn, Cd)" @default.
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- W2907694590 doi "https://doi.org/10.1016/j.jmmm.2019.01.014" @default.
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