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- W2907857576 abstract "In this chapter, the basic concepts on high-pressure phase equilibrium are introduced. Phenomenological behavior, experimental methods, and theoretical modeling are described in the chapter to give a general overview of the problem. For the description of the different processes that take advantage of the use of high-pressure conditions, the knowledge of thermodynamic properties is essential. Some particular processes can require very high pressures for special applications, but pressures between 100 and 1000 bar can be found easily in different industrial processes. Typical examples are the synthesis of ammonia, the synthesis of methanol and the production of low-density polyethylene, and also in analytical techniques as high-pressure liquid chromatography. Other important implications are for the storage and transportation of fluids and enhanced oil recovery. In the high-density region, the fluids exhibit properties similar to those of liquids, leading to high loading of solutes, high molecular diffusivity, and low viscosity. The solubility of a given solute appears to be practically exponential in density, consequently very small pressure variations result in large changes of solubility." @default.
- W2907857576 created "2019-01-11" @default.
- W2907857576 creator A5015131739 @default.
- W2907857576 creator A5042744344 @default.
- W2907857576 date "2001-01-01" @default.
- W2907857576 modified "2023-09-27" @default.
- W2907857576 title "Thermodynamic Properties at High Pressure" @default.
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- W2907857576 doi "https://doi.org/10.1016/s0926-9614(01)80020-4" @default.
- W2907857576 hasPublicationYear "2001" @default.
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