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- W2908015404 abstract "Polydiacetylenes are a class of conjugated polymers exhibiting unique color and fluorescence properties and employed as useful sensing vehicles. Here we demonstrate for the first time that the dielectric properties of polydiacetylenes can be exploited for vapor sensing. Specifically, electrodes coated with polydiacetylenes, embedded within a porous polyvinylpyrrolidone (PVP) matrix, exhibit significant capacitance transformations upon exposure to different vapors. The capacitive response of the polydiacetylene/PVP films depended upon both the structures of the diacetylene monomer and the extent of ultraviolet irradiation (i.e., polymerization), underscoring a unique sensing mechanism affected by conjugation, structure, and dielectric properties of the polydiacetylene/polymer matrix. Importantly, the variability of polydiacetylene structures allows vapor identification through an array-based pattern recognition (i.e., artificial nose). This study opens new avenues for applications of polydiacetylene systems, particularly pointing to their dielectric properties as powerful sensing determinants." @default.
- W2908015404 created "2019-01-11" @default.
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- W2908015404 date "2019-01-04" @default.
- W2908015404 modified "2023-10-18" @default.
- W2908015404 title "Polydiacetylene Capacitive Artificial Nose" @default.
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- W2908015404 doi "https://doi.org/10.1021/acsami.8b20930" @default.
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