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- W2908074596 abstract "Near-infrared (NIR) emitting persistent phosphors of Cr3+-doped zinc gallogermanate have emerged for in vivo bioimaging with the advantage of no need for in situ excitation. However, it is challenging to synthesize well-dispersed and uniform spherical particles with high brightness, high resolution, and distinguished NIR long afterglow. In this work, Zn3Ga2Ge2O10:Cr3+ (ZGGC) monospheres were directly synthesized by a facile hydrothermal method with the assistance of citric anions (Cit3-), which emit an NIR emission at ∼696 nm and exhibit excellent NIR-persistent luminescence with rechargeability. Controlled experiments indicated that the shape evolution of the ZGGC product is significantly affected by Cit3-, solution pH, and the duration and temperature of hydrothermal reaction. Furthermore, compositional influence on the crystal structure, bandgap, trap depth, and luminescence characteristics of ZnyGa2Ge2O10-δ:Cr3+ (y = 2.8, 3.0, 3.2) were investigated in detail, which allows us to construct an energy level diagram of the ZGGC host, Cr3+ ions, and electron traps. It was found that the bandgap and conduction-band minimum (CBM) are significantly affected by the Zn content, while the valence-band maximum (VBM) is not. The y = 3.0 sample exhibited the best persistent luminescence, owing to its deepest defects. The ZGGC-NH2 prepared through surface functionalization of ZGGC spheres showed distinguished NIR long afterglow, low toxicity, and great potential for in vitro cell imaging and in vivo bioimaging in the absence of excitation. Moreover, the persistent luminescence signal from the ZGGC-NH2 can be repeated in vivo through in situ recharge with external excitation of a red LED lamp, indicating that the ZGGC-NH2 is suitable for applications in long-term in vivo imaging." @default.
- W2908074596 created "2019-01-11" @default.
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- W2908074596 date "2018-12-28" @default.
- W2908074596 modified "2023-10-14" @default.
- W2908074596 title "Zn<sub>3</sub>Ga<sub>2</sub>Ge<sub>2</sub>O<sub>10</sub>:Cr<sup>3+</sup> Uniform Microspheres: Template-Free Synthesis, Tunable Bandgap/Trap Depth, and <i>In Vivo</i> Rechargeable Near-Infrared-Persistent Luminescence" @default.
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- W2908074596 doi "https://doi.org/10.1021/acsabm.8b00734" @default.
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