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- W2908194711 abstract "Abstract Ten tripod-shaped electrochromic materials (compound 1–10) were designed and synthesized by esterification of 4,4′,4″-s-triazine-2,4,6-triyl-tribenzoic acid with different alcohols and phenols. These materials have a 2,4,6-triphenyl-1,3,5-triazine core and three ester side arms, forming an electron donor–π-acceptor structure. The electrochemical and optical properties of 1–10 were characterized by cyclic voltammetry and ultraviolet–visible spectroelectrochemistry. The conjugated structure of 1–10 markedly influenced their electrochemical properties. Electrochromic devices containing some of these compounds (1, 2, 4, 5, and 10) displayed intense color changes, fast switching times ( 60%), good switching stability, high optical density (>1.0), and high coloring efficiency (>1000 cm2 C−1). The colored state of these devices strongly depended on the conjugated structure of the tripod-shaped component. Short chain lengths (compounds 1 and 2) and electron-donating groups (compounds 4, 5, 8, and 10) were beneficial to electrochromic properties, whereas a longer chain length (compound 3) and electron-withdrawing groups (compounds 6 and 9) adversely affected electrochromic properties." @default.
- W2908194711 created "2019-01-11" @default.
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- W2908194711 date "2019-04-01" @default.
- W2908194711 modified "2023-09-24" @default.
- W2908194711 title "Electrochromic 2,4,6-triphenyl-1,3,5-triazine based esters with electron donor-acceptor structure" @default.
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- W2908194711 doi "https://doi.org/10.1016/j.orgel.2018.12.041" @default.
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