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- W2908201317 abstract "Developing a new detection system for reliable recognition of threatening organophosphate poisons (OPs) is a challenging subject for analysts to control their undesirable effects. Here, a sensitive analytical assay for OPs was reported based on the high mimetic behavior of layered double hydroxides supported ZIF-8 nanocomposite ([email protected]). The well-known inhibiting effect of OP analytes on the enzymatic activity of acetylcholinesterase (AChE) was exerted to gain a suitable selectivity. Following that, efficient chemiluminescence (CL) system assisted by [email protected] was employed to monitor the variation in the amount of produced H2O2. It is found that the synthesized [email protected] possess a high effective peroxidase-like activity and can remarkably enhance the emission of the ultra-weak rhodamine B (RhoB)-H2O2 CL reaction. More studied was done using fluorometric to ratify the mimetic properties of [email protected] nanocomposite. The high catalytic effect of developed nanocomposite assured the high efficacy of the CL system to detect the small changes in H2O2 concentration, resulting in a high sensitivity in the detection of OPs. The low-priced and simple synthesized [email protected] catalyst, as well as a simple and easy-to-use CL system can be beneficial in the development of an on-site and portable detection tools. A wide linear range of 0.5–300 nM was achieved for the determination of diazinon (as a model OP), and the detection limit was as low as 0.22 nM. The method showed high reproducibility and was reassured by its application for the analysis of environmental samples." @default.
- W2908201317 created "2019-01-11" @default.
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- W2908201317 creator A5031059481 @default.
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- W2908201317 creator A5039505371 @default.
- W2908201317 date "2019-04-01" @default.
- W2908201317 modified "2023-10-04" @default.
- W2908201317 title "Highly sensitive chemiluminescence sensing system for organophosphates using mimic LDH supported ZIF-8 nanocomposite" @default.
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- W2908201317 doi "https://doi.org/10.1016/j.snb.2018.12.147" @default.
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