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• W2908207923 endingPage "18802" @default.
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• W2908207923 abstract "We report syntheses, crystal and electronic structures, and characterization of three new hybrid organic-inorganic halides (R)ZnBr3(DMSO), (R)2CdBr4·DMSO, and (R)CdI3(DMSO) (where (R) = C6(CH3)5CH2N(CH3)3, and DMSO = dimethyl sulfoxide). The compounds can be conveniently prepared as single crystals and bulk polycrystalline powders using a DMSO-methanol solvent system. On the basis of the single-crystal X-ray diffraction results carried out at room temperature and 100 K, all compounds have zero-dimensional (0D) crystal structures featuring alternating layers of bulky organic cations and molecular inorganic anions based on a tetrahedral coordination around group 12 metal cations. The presence of discrete molecular building blocks in the 0D structures results in localized charges and tunable room-temperature light emission, including white light for (R)ZnBr3(DMSO), bluish-white light for (R)2CdBr4·DMSO, and green for (R)CdI3(DMSO). The highest photoluminescence quantum yield (PLQY) value of 3.07% was measured for (R)ZnBr3(DMSO), which emits cold white light based on the calculated correlated color temperature (CCT) of 11,044 K. All compounds exhibit fast photoluminescence lifetimes on the timescale of tens of nanoseconds, consistent with the fast luminescence decay observed in π-conjugated organic molecules. Temperature dependence photoluminescence study showed the appearance of additional peaks around 550 nm, resulting from the organic salt emission. Density functional theory calculations show that the incorporation of both the low-gap aromatic molecule R and the relatively electropositive Zn and Cd metals can lead to exciton localization at the aromatic molecular cations, which act as luminescence centers." @default.
• W2908207923 created "2019-01-11" @default.
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• W2908207923 date "2018-12-28" @default.
• W2908207923 modified "2023-10-15" @default.
• W2908207923 title "Broadband Emission in Hybrid Organic–Inorganic Halides of Group 12 Metals" @default.
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• W2908207923 cites W1968405718 @default.
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• W2908207923 cites W1972590175 @default.
• W2908207923 cites W1975592620 @default.
• W2908207923 cites W1981368803 @default.
• W2908207923 cites W1984089187 @default.
• W2908207923 cites W2007395042 @default.
• W2908207923 cites W2020630923 @default.
• W2908207923 cites W2023390323 @default.
• W2908207923 cites W2026397322 @default.
• W2908207923 cites W2047568851 @default.
• W2908207923 cites W2050310840 @default.
• W2908207923 cites W2051409547 @default.
• W2908207923 cites W2059287621 @default.
• W2908207923 cites W2060440976 @default.
• W2908207923 cites W2062002268 @default.
• W2908207923 cites W2066630749 @default.
• W2908207923 cites W2077095144 @default.
• W2908207923 cites W2083222334 @default.
• W2908207923 cites W2086112069 @default.
• W2908207923 cites W2086981302 @default.
• W2908207923 cites W2113353077 @default.
• W2908207923 cites W2123857657 @default.
• W2908207923 cites W2132454074 @default.
• W2908207923 cites W2132808501 @default.
• W2908207923 cites W2145883851 @default.
• W2908207923 cites W2158821783 @default.
• W2908207923 cites W2166490357 @default.
• W2908207923 cites W2167590372 @default.
• W2908207923 cites W2191811958 @default.
• W2908207923 cites W2291816733 @default.
• W2908207923 cites W2313854225 @default.
• W2908207923 cites W2327721819 @default.
• W2908207923 cites W2332549384 @default.
• W2908207923 cites W2342802384 @default.
• W2908207923 cites W2347149592 @default.
• W2908207923 cites W2416845862 @default.
• W2908207923 cites W2471425766 @default.
• W2908207923 cites W2514183635 @default.
• W2908207923 cites W2525658420 @default.
• W2908207923 cites W2571434002 @default.
• W2908207923 cites W2587159679 @default.
• W2908207923 cites W2591503170 @default.
• W2908207923 cites W2597250731 @default.
• W2908207923 cites W2605218835 @default.
• W2908207923 cites W2620639919 @default.
• W2908207923 cites W2624819177 @default.
• W2908207923 cites W2729523528 @default.
• W2908207923 cites W2737381275 @default.
• W2908207923 cites W2741663605 @default.
• W2908207923 cites W2766522659 @default.
• W2908207923 cites W2767983659 @default.
• W2908207923 cites W2768259150 @default.
• W2908207923 cites W2768667191 @default.
• W2908207923 cites W2772443558 @default.
• W2908207923 cites W2775444220 @default.
• W2908207923 cites W2788074397 @default.
• W2908207923 cites W2789798390 @default.
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• W2908207923 doi "https://doi.org/10.1021/acsomega.8b02883" @default.
• W2908207923 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6643692" @default.
• W2908207923 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31458442" @default.
• W2908207923 hasPublicationYear "2018" @default.
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