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• W2908666189 endingPage "523" @default.
• W2908666189 startingPage "519" @default.
• W2908666189 abstract "We describe herein an organocatalytic, diastereo- and enantioselective [6 + 2]-cycloaddition toward the synthesis of densely substituted 2,3-dihydro-1H-pyrrolizines bearing three contiguous stereogenic centers which are obtained with good yields, as single diastereomers, and with excellent enantioselectivity. A crucial feature of this one-step process leading to a prominent structural motif in many biologically active natural products is a BINOL-derived phosphoric acid catalyzed reaction of 1H-pyrrole-2-yl carbinols with 2-vinylindoles via the corresponding hydrogen-bonded chiral 2-methide-2H-pyrroles." @default.
• W2908666189 created "2019-01-25" @default.
• W2908666189 creator A5005127669 @default.
• W2908666189 creator A5058013131 @default.
• W2908666189 date "2019-01-08" @default.
• W2908666189 modified "2023-10-12" @default.
• W2908666189 title "Brønsted Acid Catalyzed [6 + 2]-Cycloaddition of 2-Vinylindoles with in Situ Generated 2-Methide-2<i>H</i>-pyrroles: Direct, Catalytic, and Enantioselective Synthesis of 2,3-Dihydro-1<i>H</i>-pyrrolizines" @default.
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• W2908666189 doi "https://doi.org/10.1021/acs.orglett.8b03833" @default.
• W2908666189 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30620204" @default.
• W2908666189 hasPublicationYear "2019" @default.
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