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• W2908681036 abstract "Three 3D Cd(Ⅱ) metal-organic frameworks(MOFs), namely, {[Cd3(L)(OH)(H2O)3]n·2H2O} (1), {Cd5(L)2(H2O)9}n (2) and {Cd2(L)(bib)(NH4)}n (3), have been synthesized based on H5L and cadmium ion under hydrothermal conditions (H5L = 3,5-di(2′,5′-dicarboxylpyl)benozoic acid, bib = 1,4-bis(1-imidazoly)benzene), and characterized by IR spectrum analysis, powder X-ray diffraction analysis (PXRD) and thermogravimetric analysis (TGA). X-ray single crystal diffraction analyses showed that complex 1 is a porous 3D 4-connected net with the point symbol of {4.65} with the trinuclear [Cd3(OH)(COO)5] SBUs, complex 2 displays a 3D framework 7-connected net with the point symbol of {33.412.55.6} with the pentanuclear [Cd5(COO)10(H2O)9] SBUs and complex 3 presents a porous 3D 4,6-connected net with the point symbol of {43.610.82}{43.63}. Furthermore, fluorescent measurements indicated that 1 and 2 have potential application in the detection for Fe3+, CrO42- and Cr2O72- ions in aqueous solution. Gas sorption properties exhibited that complex 1 has better hydrogen storage performance." @default.
• W2908681036 created "2019-01-25" @default.
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• W2908681036 date "2019-03-01" @default.
• W2908681036 modified "2023-10-16" @default.
• W2908681036 title "Gas adsorption and fluorescent sensing properties of three metal-organic frameworks based on 3,5-di(2′,5′-dicarboxylphenyl)benozoic acid and cadmium ions" @default.
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• W2908681036 doi "https://doi.org/10.1016/j.jssc.2019.01.008" @default.
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