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- W2908764518 endingPage "2772" @default.
- W2908764518 startingPage "2767" @default.
- W2908764518 abstract "A metal-free and photo-free method for the perfluoroalkylative pyridylation of alkenes has been developed via a combination of computational and experimental studies. Density functional theory calculations and control experiments indicate that the homolysis of Rf-X (X = Br, I) bonds by the 4-cyanopyridine-boryl radicals in situ generated from 4-cyanopyridine and B2pin2 is the key step. Sequential addition of Rf radicals to alkenes and the selective cross-coupling of the resulting alkyl radicals and 4-cyanopyridine-boryl radicals gives alkene difunctionalization products with a quaternary carbon center. This method exhibits a broad substrate scope and good functional group compatibility." @default.
- W2908764518 created "2019-01-25" @default.
- W2908764518 creator A5000563498 @default.
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- W2908764518 creator A5031892138 @default.
- W2908764518 creator A5045248246 @default.
- W2908764518 creator A5080738689 @default.
- W2908764518 date "2019-01-01" @default.
- W2908764518 modified "2023-10-11" @default.
- W2908764518 title "Perfluoroalkylative pyridylation of alkenes<i>via</i>4-cyanopyridine-boryl radicals" @default.
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