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- W2908955985 abstract "The synthesis of a new functional group in the form of selenyl-substituted aziridines is described. Selenoaziridines are stereoselectively prepared by functionalization of intact aziridine precursors involving radical and anionic intermediates. Radicals are generated from cis-N-Ts iodoaziridines by activation of the C–I bond using alkoxides as a source of single electrons. These form predominantly trans-substituted selenoaziridines dependent on the size of the diselenide. cis-Aziridinyllithiums generated by Li–I exchange also react with diselenides stereospecifically to form a range of cis-selenoaziridines. Proposals for the stereochemical outcome are presented." @default.
- W2908955985 created "2019-01-25" @default.
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- W2908955985 date "2019-01-10" @default.
- W2908955985 modified "2023-09-26" @default.
- W2908955985 title "Synthesis of Selenoaziridines: A Study on Stereochemical Outcomes of the Reaction of Aziridine Radicals and Anions Generated from Iodoaziridines" @default.
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- W2908955985 doi "https://doi.org/10.1021/acsomega.8b03019" @default.
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