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- W2909023213 endingPage "558" @default.
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- W2909023213 abstract "A catalytic aza-Nazarov cyclization between 3,4-dihydroisoquinolines and α,β-unsaturated acyl chlorides has been developed to access α-methylene-γ-lactam products in good yields (up to 79%) as single diastereomers. The reactions proceed efficiently when AgOTf is used as an anion exchange catalyst with a 20 mol % loading at 80 °C. Computational studies were performed to investigate the reaction mechanism, and the findings support the role of the −TMS group in reducing the reaction barrier of the key cyclization step." @default.
- W2909023213 created "2019-01-25" @default.
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- W2909023213 date "2019-01-08" @default.
- W2909023213 modified "2023-10-17" @default.
- W2909023213 title "Aza-Nazarov Cyclization Reactions via Anion Exchange Catalysis" @default.
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- W2909023213 doi "https://doi.org/10.1021/acs.orglett.8b03886" @default.
- W2909023213 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30985150" @default.
- W2909023213 hasPublicationYear "2019" @default.
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