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- W2909303183 abstract "Abstract A series of functionalized amphiphilic diblock fullerene derivatives C 60 ‐4TPB, C 60 ‐2DPE, C 60 ‐4HTPB, C 60 ‐PHFBS, and C 60 ‐2BEFPE are developed and applied as the modification layers on zinc oxide (ZnO) in inverted organic solar cell (OSC) devices. By spin‐coating ZnO, the fullerene derivatives layer can reduce the work function of ZnO via modulation of the interfacial dipoles. When introducing solvent treatment by toluene during the preparation of films, the order of the fullerene derivatives layer are clearly increased, which are supported by X‐ray diffraction and contact angle of water measurements. The OSCs devices modified with those fullerene derivatives show power conversion efficiency of 8.62%, 9.21%, 8.86%, 9.14%, and 9.15% based on poly‐[4,8‐bis(5‐(2‐ethylhexyl)‐thiophen‐2‐yl)benzo[1,2‐b:4,5‐b′]‐dithiophene‐alt‐3‐fluoro thieno‐[3,4‐b] thiophene‐2‐carboxylate] (PTB7‐Th) and [6,6]‐phenyl‐C 71 ‐butyric acid methyl ester (PC 71 BM) blend, respectively. All the results indicate that the development of diblock amphiphilic fullerene derivatives opens a new opportunity to modify the present defects of ZnO by simultaneously modulating interfacial work functions, the wetting properties of the interlayer, and the active layer." @default.
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- W2909303183 date "2019-01-13" @default.
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- W2909303183 title "Synthesis and Application of Functionalized Diblock Amphiphilic Fullerene Derivatives" @default.
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