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- W2909603327 endingPage "528" @default.
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- W2909603327 abstract "Abstract One of the most beneficial aspects of organic materials is their ability to fabricate devices from solutions at moderate temperatures. Not only does this enable high-speed coating of large device substrates, it also minimizes the energetic and equipment costs of fabricating devices. However, this fabrication also limits control of the crystallization process. Nowhere is this more prevalent than in organic photovoltaics (OPVs), which require an intimately mixed bulk heterojunction (BHJ) blend of two or more organic materials, which is commonly accomplished by casting from a blend solution. The missing link between processing conditions and device performance lies in the microstructure. This chapter discusses traditional and emerging techniques for characterizing the microstructure of organic thin films at multiple length scales. First, it introduces the microstructural properties of organic films that are important for determining organic photovoltaic device (PVD) performance. The organization of the chapter is in three sections, based on the aspect to be measured: first, domain sizes in blend films; second, domain composition; and finally, the intermolecular packing or crystal structure within a domain. Each measurement technique is briefly introduced, and its strengths and limitations are analyzed. The final section of the chapter summarizes the techniques and discusses how they may be used to develop design rules for maximizing efficiency in devices." @default.
- W2909603327 created "2019-01-25" @default.
- W2909603327 creator A5039478299 @default.
- W2909603327 creator A5051528714 @default.
- W2909603327 date "2019-01-01" @default.
- W2909603327 modified "2023-09-26" @default.
- W2909603327 title "Organic thin-film microstructure characterization" @default.
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