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- W2909667595 endingPage "8302" @default.
- W2909667595 startingPage "8291" @default.
- W2909667595 abstract "Recent advances in the synthetic chemistry of atomically precise metal nanoclusters (NCs) have significantly broadened the accessible sizes and structures. Such particles are well defined and have intriguing properties, thus, they are attractive for catalysis. Especially, those NCs with identical size but different core (or surface) structure provide unique opportunities that allow the specific role of the core and the surface to be mapped out without complication by the size effect. Herein, we summarize recent work with isomeric Aun NCs protected by ligands and isostructural NCs but with different surface ligands. The highlighted work includes catalysis by spherical and rod-shaped Au25 (with different ligands), quasi-isomeric Au28 (SR)20 with different R groups, structural isomers of Au38 (SR)24 (with identical R) and Au38 S2 (SR)20 with body-centred cubic (bcc) structure, and isostructural [Au38 L20 (PPh3 )4 ]2+ (different L). These isomeric and/or isostructural NCs have provided valuable insights into the respective roles of the kernel, surface staples, and the type of ligands on catalysis. Future studies will lead to fundamental advances and development of tailor-made catalysts." @default.
- W2909667595 created "2019-01-25" @default.
- W2909667595 creator A5000578374 @default.
- W2909667595 creator A5005780047 @default.
- W2909667595 creator A5020512076 @default.
- W2909667595 creator A5020746135 @default.
- W2909667595 creator A5021523686 @default.
- W2909667595 creator A5023404026 @default.
- W2909667595 creator A5024305091 @default.
- W2909667595 creator A5027366619 @default.
- W2909667595 creator A5069371386 @default.
- W2909667595 date "2019-03-27" @default.
- W2909667595 modified "2023-10-11" @default.
- W2909667595 title "Atomically Tailored Gold Nanoclusters for Catalytic Application" @default.
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