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- W2910284652 abstract "Design and synthesis of the hydrogen-bonded liquid crystalline (HBLC) mixtures are accomplished from diglycolic acid and 4-n-alkoxybenzoic acid (n = 9–12). Spectroscopic characterization such as UV–Vis, FT-IR, and DSC has supported the presence of molecular geometry of HBLC mixtures. Thermochromic effect is analyzed for the polarizing filter applications. Induced new phases (Smectic X and Smectic Cr) and their first-order transitions are confirmed through DSC along with its corresponding textures using polarizing optical microscope. Furthermore, the induced re-entrant smectic ordering due to the lone pair to π* transition is reported using density functional theory (DFT) studies. Dipole moment studies (DFT) clearly give a strong evidence of the existence of nematic and smectic phases due to the monopole–dipole interaction in the present HBLC mixtures. Band gap of the present HBLCs is 5.175 eV, which is calculated by the HOMO–LUMO analysis and is validated using experimental observations. Liquid crystal parameters such as transition temperature, enthalpy values, stability factor and tilt angles are reported." @default.
- W2910284652 created "2019-01-25" @default.
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- W2910284652 date "2019-01-17" @default.
- W2910284652 modified "2023-09-26" @default.
- W2910284652 title "Experimental and computational studies on induced thermochromic effect and re-entrant smectic phase in linear double hydrogen-bonded binary liquid crystal mixtures" @default.
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- W2910284652 doi "https://doi.org/10.1080/01411594.2019.1566546" @default.
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