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- W2910302017 abstract "Abstract Chitin shows poor solubility and processability because of its high crystallinity. However, nanofibrillation of chitin has attracted much research attention because of its tendency towards effective materialization and functionalization. We have earlier reported that a self‐assembled chitin nanofiber (ChNF) film is obtained from a chitin/1‐allyl‐3‐methylimidazolium bromide (AMIMBr) ion gel by regeneration with methanol, followed by filtration. The film was constructed by high entanglement of ChNFs during the isolation procedure. In this study, we examined the fabrication of a semi‐crystalline chitin film by hexanoylation on ChNFs under dispersion conditions. After the reaction, the resulting chitin hexanoate reformed the film, but showed a reduced nanofiber morphology, the extent of which depended on the degree of substitution. The fusion of amorphous phases among crystalline phases by preferential hexanoylation at ChNF surfaces produced the semi‐crystalline film with flexible property." @default.
- W2910302017 created "2019-01-25" @default.
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- W2910302017 date "2019-01-18" @default.
- W2910302017 modified "2023-09-25" @default.
- W2910302017 title "Fabrication of Semi-crystalline Film by Hexanoylation on Self-assembled Chitin Nanofibers" @default.
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- W2910302017 doi "https://doi.org/10.1002/slct.201803779" @default.
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