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• W2910363829 startingPage "181" @default.
• W2910363829 abstract "Nanozymes' activities could be regulated by a simple and effective pH change in an in situ manner. In this work, for the first time, the peroxidase-like activity of Ni/Co layered double hydroxides (LDHs) was regulated via the alkaline-promoted reaction of fluorogenic substrate homovanillic acid and H2O2, and a promising tool for pH sensing was developed over the pH range of 8.3-9.6. As peroxidase nanozyme model, Ni/Co LDHs showed ease of preparation, low-cost, and water-solubility, which played an important role in this luminescence system. Based on the pH-dependent regulation of the Ni/Co LDHs activity, we constructed the bioassay platform for the determination urea, urease, penicillin G, and penicillinase with a wide linear range of 17-1000 µM, 3.3-270 mU mL-1, 3.3-1300 µM and 3.3-100 mU mL-1, respectively. This study not only demonstrated the alkaline-promoted modulation the nanozymes' activities, but also established a facile approach to develop novel bioassays." @default.
• W2910363829 created "2019-01-25" @default.
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• W2910363829 date "2019-05-01" @default.
• W2910363829 modified "2023-10-15" @default.
• W2910363829 title "Alkaline-promoted regulation of the peroxidase-like activity of Ni/Co LDHs and development bioassays" @default.
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• W2910363829 doi "https://doi.org/10.1016/j.talanta.2019.01.021" @default.
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