FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2910567912> ?p ?o ?g. }

• W2910567912 endingPage "2458" @default.
• W2910567912 startingPage "2452" @default.
• W2910567912 abstract "The monomeric molecular aluminium(i) complex 1 [{(ArNCMe)2CH}Al] (Ar = 2,6-di-iso-propylphenyl) reacts with a series of terminal and strained alkenes including ethylene, propylene, allylbenzene and norbornene to form alkene bound products. Remarkably all these reactions are reversible under mild conditions (298-353 K) with alkene binding being disfavoured at higher temperatures due to the positive reaction entropy. Van't Hoff analyses have allowed quantification of the binding events with . Calculations and single crystal X-ray diffraction studies are consistent with the alkene bound species being metallocyclopropane complexes. Alkene binding involves a reversible redox process with changes from the +1 to +3 aluminium oxidation state. Under more forcing conditions the metallocyclopropane complexes undergo non-reversible allylic C-H bond activation to generate aluminium(iii) allyl hydride complexes. This represents a rare example of redox-based main group reactivity in which reversible substrate binding is followed by a further productive bond breaking event. Analysis of the mechanism reveals a reaction network in which alkene dissociation and reformation of 1 is required for allylic C-H activation, a realisation that has important implications for the long-term goal of developing redox-based catalytic cycles with main group compounds." @default.
• W2910567912 created "2019-01-25" @default.
• W2910567912 creator A5034836508 @default.
• W2910567912 creator A5078228822 @default.
• W2910567912 creator A5087959120 @default.
• W2910567912 date "2019-01-01" @default.
• W2910567912 modified "2023-10-10" @default.
• W2910567912 title "Reversible alkene binding and allylic C–H activation with an aluminium(<scp>i</scp>) complex" @default.
• W2910567912 cites W1966080154 @default.
• W2910567912 cites W1967563275 @default.
• W2910567912 cites W1990691121 @default.
• W2910567912 cites W2001212120 @default.
• W2910567912 cites W2007141562 @default.
• W2910567912 cites W2012255189 @default.
• W2910567912 cites W2022670739 @default.
• W2910567912 cites W2023336317 @default.
• W2910567912 cites W2036885659 @default.
• W2910567912 cites W2055846507 @default.
• W2910567912 cites W2060013781 @default.
• W2910567912 cites W2060732591 @default.
• W2910567912 cites W2064830477 @default.
• W2910567912 cites W2080884639 @default.
• W2910567912 cites W2081054814 @default.
• W2910567912 cites W2087490887 @default.
• W2910567912 cites W2093947989 @default.
• W2910567912 cites W2098677629 @default.
• W2910567912 cites W2102313763 @default.
• W2910567912 cites W2104587737 @default.
• W2910567912 cites W2104951335 @default.
• W2910567912 cites W2105722596 @default.
• W2910567912 cites W2112129576 @default.
• W2910567912 cites W2119831337 @default.
• W2910567912 cites W2129134424 @default.
• W2910567912 cites W2131376639 @default.
• W2910567912 cites W2143453620 @default.
• W2910567912 cites W2143885998 @default.
• W2910567912 cites W2297465350 @default.
• W2910567912 cites W2320538382 @default.
• W2910567912 cites W2329313066 @default.
• W2910567912 cites W2330902047 @default.
• W2910567912 cites W2400871630 @default.
• W2910567912 cites W2462152538 @default.
• W2910567912 cites W2488418926 @default.
• W2910567912 cites W2502764884 @default.
• W2910567912 cites W2508877092 @default.
• W2910567912 cites W2531802175 @default.
• W2910567912 cites W2623228626 @default.
• W2910567912 cites W2773682022 @default.
• W2910567912 cites W2788536055 @default.
• W2910567912 cites W2791359566 @default.
• W2910567912 cites W2796973957 @default.
• W2910567912 cites W2797749276 @default.
• W2910567912 cites W2806157750 @default.
• W2910567912 cites W2883754955 @default.
• W2910567912 cites W2887239015 @default.
• W2910567912 cites W2899458506 @default.
• W2910567912 cites W3137283670 @default.
• W2910567912 cites W4240573474 @default.
• W2910567912 doi "https://doi.org/10.1039/c8sc04865g" @default.
• W2910567912 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6388093" @default.
• W2910567912 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30881673" @default.
• W2910567912 hasPublicationYear "2019" @default.
• W2910567912 type Work @default.
• W2910567912 sameAs 2910567912 @default.
• W2910567912 citedByCount "64" @default.
• W2910567912 countsByYear W29105679122019 @default.
• W2910567912 countsByYear W29105679122020 @default.
• W2910567912 countsByYear W29105679122021 @default.
• W2910567912 countsByYear W29105679122022 @default.
• W2910567912 countsByYear W29105679122023 @default.
• W2910567912 crossrefType "journal-article" @default.
• W2910567912 hasAuthorship W2910567912A5034836508 @default.
• W2910567912 hasAuthorship W2910567912A5078228822 @default.
• W2910567912 hasAuthorship W2910567912A5087959120 @default.
• W2910567912 hasBestOaLocation W29105679121 @default.
• W2910567912 hasConcept C120095180 @default.
• W2910567912 hasConcept C142724271 @default.
• W2910567912 hasConcept C155647269 @default.
• W2910567912 hasConcept C161790260 @default.
• W2910567912 hasConcept C166940927 @default.
• W2910567912 hasConcept C178790620 @default.
• W2910567912 hasConcept C179104552 @default.
• W2910567912 hasConcept C185592680 @default.
• W2910567912 hasConcept C204787440 @default.
• W2910567912 hasConcept C2776254738 @default.
• W2910567912 hasConcept C2776910235 @default.
• W2910567912 hasConcept C2780547246 @default.
• W2910567912 hasConcept C521977710 @default.
• W2910567912 hasConcept C55904794 @default.
• W2910567912 hasConcept C71240020 @default.
• W2910567912 hasConcept C71924100 @default.
• W2910567912 hasConcept C75473681 @default.
• W2910567912 hasConcept C8010536 @default.
• W2910567912 hasConceptScore W2910567912C120095180 @default.
• W2910567912 hasConceptScore W2910567912C142724271 @default.
• W2910567912 hasConceptScore W2910567912C155647269 @default.
• W2910567912 hasConceptScore W2910567912C161790260 @default.
• W2910567912 hasConceptScore W2910567912C166940927 @default.

• next