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• W2910596473 abstract "A series of different contents of glycidyl methacrylate (GMA)-grafted natural rubber (GNR) copolymers were fabricated via green bulk melt-grafting reactions, and super-tough bio-based poly (lactic acid) (PLA)/GNR thermoplastic vulcanizates (TPVs) were achieved by in-situ dynamic vulcanization. Increasing the graft yield, gel fraction, and crosslinking density of GNR vulcanizates effectively improved the ductility of the PLA/GNR TPVs, while prolonging the dynamic vulcanization time and increasing the GMA graft yield led to a notable enhancement in the impact toughness of the PLA/GNR TPVs. PLA/30 wt % GNR TPVs exhibited a significantly increased elongation (410%) and notched impact strength (73.2 kJ/m2), which were 40 and 15 times higher than those of the PLA/30 wt % NR TPVs, respectively. The new bio-based PLA/GNR TPVs offer promise as replacements for petroleum-based polymers in the automotive, 3D printing, and packaging fields." @default.
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• W2910596473 date "2019-01-18" @default.
• W2910596473 modified "2023-09-27" @default.
• W2910596473 title "The Microstructure of GNR and the Mechanical Properties of Biobased PLA/GNR Thermoplastic Vulcanizates with Excellent Toughness" @default.
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• W2910596473 doi "https://doi.org/10.3390/ma12020294" @default.
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