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- W2910804920 abstract "A three‐dimensional Cd 2+ framework ( 1 ) with wide one‐dimensional hexagonal channels was prepared based on a tripodal tricarboxylate ligand possessing nitrogen donor atoms. The Cd atoms form a chain structure bridged by carboxylates and aqua ligands. Upon Mg 2+ ion capture, the fluorescence emission of this porous material was 5.2 times greater than its Mg 2+ ‐free fluorescence. To the best of our knowledge, such enhancement has not been previously reported for metal–organic framework sensory systems. The sensing performance of 1 is reversible over repeated cycles of Mg 2+ inclusion and release, revealing the reusability of this material. In the presence of other tested metal ions, Mg 2+ ions were selectively detected owing to the operation of this “turn‐on” mechanism. Thus, this platform is a promising sensor material for selective Mg 2+ ion recognition." @default.
- W2910804920 created "2019-01-25" @default.
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- W2910804920 date "2019-01-11" @default.
- W2910804920 modified "2023-09-25" @default.
- W2910804920 title "Synthesis, Structure, and Photoluminescence Properties of a Metal‐Organic Framework with Hexagonal Channels: Selective Turn‐On Sensing for Mg <sup>2+</sup> Ion" @default.
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- W2910804920 doi "https://doi.org/10.1002/ejic.201801291" @default.
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