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- W2910962079 abstract "A commercially available and stable ruthenium dodecacarbonyl catalyst (Ru3(CO)12) allows very efficient and convenient access to functionalized silsesquioxanes (SQs) containing siloxane moiety (Si-O-Si) via dehydrogenative coupling of POSS-silanols with hydrosilanes. With the aid of SiH-containing silsesquioxanes, an unprecedented one-pot procedure has been revealed, and the usefulness of this approach was demonstrated by the synthesis of various derivatives via O-silylation, as well as C═C and C═N hydrosilylation." @default.
- W2910962079 created "2019-01-25" @default.
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- W2910962079 date "2019-01-10" @default.
- W2910962079 modified "2023-10-18" @default.
- W2910962079 title "Ru-Catalyzed Dehydrogenative Silylation of POSS-Silanols with Hydrosilanes: Its Introduction to One-Pot Synthesis" @default.
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- W2910962079 doi "https://doi.org/10.1021/acs.inorgchem.8b02645" @default.
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