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- W2911227209 abstract "Abstract Several bis(phosphinite) (POCOP) group 10 metal pincer complexes bearing a mercapto‐ o ‐carborane auxiliary ligand, [2,6‐( i Pr 2 PO) 2 C 6 H 3 ]MS‐ o ‐C 2 B 10 H 11 (M=Ni, 1 ; Pd, 2 ; Pt, 3 ), were synthesized and fully characterized. Single crystal X‐ray diffraction analyses indicated that the square planar geometries of the metal centers and the POCOP pincer backbones were not significantly distorted. However, relatively weak M−S bonds were observed for all of these complexes in the solid state and a remarkable small Pt‐C ipso coupling constant (116 Hz) was detected for complex 3 during the NMR study, implying a weak Pt‐C ipso interaction in solutions. Despite the weak M−S bonds and the faint M–C ipso interaction, these complexes are relatively stable because of the steric effect of the bulky auxiliary ligand. The stability of these boron‐rich group 10 metal pincer complexes makes them potentially useful in material science." @default.
- W2911227209 created "2019-02-21" @default.
- W2911227209 creator A5010644954 @default.
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- W2911227209 creator A5047457713 @default.
- W2911227209 creator A5066523679 @default.
- W2911227209 creator A5073501391 @default.
- W2911227209 date "2019-01-25" @default.
- W2911227209 modified "2023-10-14" @default.
- W2911227209 title "Syntheses and Structures of Group 10 Metal POCOP Pincer Complexes Bearing A Mercapto-<i>o-</i> carborane Auxiliary Ligand" @default.
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