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• W2911386316 endingPage "10581" @default.
• W2911386316 startingPage "10577" @default.
• W2911386316 abstract "Abstract Hexakis(2,6‐diisopropylphenylisocyanide)tantalum is the first isocyanide analogue of the highly unstable Ta(CO) 6 and represents the only well‐defined zerovalent tantalum complex to be prepared by conventional laboratory methods. Two prior examples of homoleptic Ta 0 complexes are known, Ta(benzene) 2 and Ta(dmpe) 3 , dmpe=1,2‐bis(dimethylphosphano)ethane, but these have only been accessed via ligand co‐condensation with tantalum vapor in a sophisticated metal‐atom reactor. Consistent with its 17‐electron nature, Ta(CNDipp) 6 undergoes facile one‐electron oxidation, reduction, or disproportionation reactions. In this sense, it qualitatively resembles V(CO) 6 , the only paramagnetic homoleptic metal carbonyl isolable under ambient conditions." @default.
• W2911386316 created "2019-02-21" @default.
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• W2911386316 date "2017-07-26" @default.
• W2911386316 modified "2023-10-18" @default.
• W2911386316 title "Ta(CNDipp)₆ : An Isocyanide Analogue of Hexacarbonyltantalum(0)" @default.
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• W2911386316 doi "https://doi.org/10.1002/anie.201706323" @default.
• W2911386316 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28697283" @default.
• W2911386316 hasPublicationYear "2017" @default.
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