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- W2911404778 abstract "Two new ionic liquids (ILs), N-ethyl-N,N,N-trihexylammonium adipate (CPA6) and N-ethyl-N,N,N-trioctylammonium ethyl sulfate (ESA8), were synthesized and their chemical structures were determined by 1H and 13C NMR. The corrosion inhibition effect of the ILs on API-X60 steel in 1 M H2SO4 was studied by weight loss, Tafel polarization curves and polarization resistance. The experimental results show that the ILs were adsorbed on API-X60 steel and blocked surface active sites, reducing the corrosion rate of the metallic substrate. The ILs behaved as mixed-type corrosion inhibitors and their adsorption process obeyed the Langmuir isotherm model. The adsorption phenomenon was studied by means of the XPS, DRIFT and SEM/EDS techniques. Quantum chemical parameters were obtained from the studied ILs, calculated in vacuum and water systems, and correlated with the experimental results. The effect of organic anions on the ILs was analyzed and it was concluded that the ethyl sulfate anion presented better corrosion inhibition properties than the adipate anion; therefore, ESA8 was a more efficient corrosion inhibitor than CPA6." @default.
- W2911404778 created "2019-02-21" @default.
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- W2911404778 date "2019-04-01" @default.
- W2911404778 modified "2023-10-18" @default.
- W2911404778 title "Effect of organic anions on ionic liquids as corrosion inhibitors of steel in sulfuric acid solution" @default.
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- W2911404778 doi "https://doi.org/10.1016/j.molliq.2019.01.126" @default.
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