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• W2911448135 abstract "The rational design and facile construction of discrete heterometallic supramolecular catalysts have precipitated a surge of research interest in emulating sophisticated natural catalysts with well-defined cavities and inlaid active sites, allowing conversion of encapsulated substrates with high chemo-, regio-, and stereoselectivity. This review briefly highlights such discrete, heterometallic, coordination-driven metallacycles and metallacages obtained by the strategic utilization of a range of predesigned building blocks in the supramolecular chemist’s toolkit. The two major synthetic strategies toward these metalla-architectures are presented, and special attention has been paid to discussing both the fascinating structures and the unique catalytic performance of various heterometallic macrocycles and cages." @default.
• W2911448135 created "2019-02-21" @default.
• W2911448135 creator A5031969511 @default.
• W2911448135 creator A5081370621 @default.
• W2911448135 creator A5088250941 @default.
• W2911448135 date "2019-05-01" @default.
• W2911448135 modified "2023-10-14" @default.
• W2911448135 title "Supramolecular catalysis based on discrete heterometallic coordination-driven metallacycles and metallacages" @default.
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